The earliest material as a sizing agent is a natural rosin, since the discovery in 1807, it was used nearly 200 years, is still used, just through a variety of methods were modified, conventional sizing acidic sizing, sizing process must make use of aluminum sulfate as a retention agent, rosin acid with negative charge retention in the fiber, to achieve the purpose of sizing, though later on the rosin was modified, prepared maleic rosin saponification gum, fumaric acid rosin, acrylic rosin sizing effect greatly improved, but still must be carried out under acidic conditions sizing.
Many shortcomings due to the acidic sizing, so attention has turned to neutral sizing, 1956, the successful development of synthetic sizing agent of AKD, invented in 1968, ASA synthetic sizing agent, because of the sizing agent of the class applied for reactive glue, can and fiber reaction, keep their own, and thus do not need the help of aluminum sulfate, sizing in high PH value, neutral or alkaline sizing.
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